Basic definitions used in terms of cement and concrete
PORTLAND™ Cement: Material made by heating a mixture of limestone and clay in a kiln at about 1450°C, then grinding to a fine powder with a small addition of gypsum. Portland cement, the main subject of this project, is the most common type of cement – that is why we call it as 'basic cement'. In particular, ordinary Portland cement is the normal, grey, cement which the most of industry are familiar with. Other types of Portland cement include White Portland Cement and Sulphate Resisting Portland Cement (SRPC).
Clinker:
Portland cement is made by grinding clinker and a small amount of added gypsum. Clinker is a nodular material before it is ground up.
The nodules can be anything from 1mm to 30 mm or more in diameter.
Basic chemical information
Basic components of each Portland Cement (OPC):
Ca from CaCO3
Si from SiO2
AL from Al2O3
Fe from Fe2O3
Portland Cement (CEM I/II) is a composit of:
50% C3S Tricalciumsilicat chem. as 3CaOSiO2 Alit
25% C2S Dicalciumsilicat chem. as 2CaOSiO2 Belit
10% C3A Tricalciumaluminat chem. as 3CaOAl2O3
10% C2AF Calciumaluminatferrit chem. as 2CaOAl2O3Fe2O3
5% Gypsum chem. as CaSO4
Alite: Ca3 SiO5 in terms of its oxides is 3CaO SiO2. The CaO term is shortened to C and the SiO2 to S. The compound thus becomes C3S.
Belite: Similarly, Ca2 SiO4 is 2CaO SiO2, which is shortened to C2S.
Tricalcium Aluminate: Ca3 Al2 O6 is 3CaO Al2O3 . The Al2O3 term is shortened to A and the compound becomes C3A.
Tetracalcium Aluminoferrite: 2(Ca2 Al FeO5) is 4CaO Al2O3Fe2O3. Fe2O3 is shortened to F and the compound becomes C4AF.
Lime Saturation Factor
The LSF is a ratio of CaO to the other three main oxides. Applied to clinker, it is calculated as:
LSF=CaO / (2.8SiO2 + 1.2Al2O3 + 0.65Fe2O3)
Often this is referred to as a percentage and therefore multiplied by 100.
The LSF controls the ratio of Alite to Belite in the clinker. A clinker with a higher LSF will have a higher proportion of Alite to Belite than will be a clinker with a low LSF.
Typical LSF values in modern clinkers are 0.92-0.98, or 92%-98%.
Values above 1.0 indicate that free lime is likely to be present in the clinker. This is because, in principle, at LSF=1.0 all the free lime should have combined with Belite to form Alite. If the LSF is higher than 1.0, the surplus free lime has nothing with which to combine and will remain as free lime.
In practice, the mixing of raw materials is never perfect and there are always regions within the clinker where the LSF is locally a little above, or a little below, the target for the clinker as a whole. This means that there is almost always some residual free lime, even where the LSF is considerably below 1.0. It also means that to convert virtually all the Belite to Alite, an LSF slightly above 1.0 is needed.
The LSF calculation can also be applied to Portland cement containing clinker and gypsum if (0.7 x SO3) is subtracted from the CaO content. This calculation (0.7 x SO3) does not account for Sulphate present as clinker sulphate in the form of potassium and sodium sulphates and this will introduce a slight error. More particularly, it does not account for fine limestone or other material such as slag or fly ash in the cement. If these materials are present, calculation of the original clinker LSF becomes
more complex. Limestone can be quantified by measuring the CO2
content and the formula adjusted accordingly, but
if slag or fly ash are present, calculation of the original clinker LSF may not be conveniently practicable. To adjust the LSF formula under such more difficult circumstances needs to be involved professional chemists to train the process running staff engineers in a special course.
Silica Ratio (SR):
The silica ratio (also known as the Silica Modulus) is defined as:
SR = SiO2 / (Al2O3 + Fe2O3). A high silica ratio means that more calcium silicates are present in the clinker and less Aluminate and Ferrite. SR is typically between 2.0 and 3.0. The silica ratio is sometimes called the ‘silica modulus.’
Alumina Ratio (AR)
The alumina ratio is defined as: AR = (Al2O3 / (Fe2O3). This determines the potential relative proportions of Aluminate and Ferrite phase in the clinker. An increase in clinker AR (also sometimes written as A/F) means there will be proportionally more Aluminate and less Ferrite in the clinker. In ordinary Portland cement clinker, the AR is usually between 1 and 4.
The above three parameters are those most commonly used. A fourth, the 'Lime Combination Factor' (LCF) is the same as the LSF parameter, but with the clinker free lime content subtracted from the total CaO content. With an LCF=1.0, therefore, the maximum amount of silica is present as C3S.
Where coal is the fuel for the kiln, the raw mix composition has also to take into account the effect of coal ash, as much of the ash will become incorporated into the clinker. The quantity of ash is enough to have a significant effect on clinker composition - ash may represent perhaps 2%-3%, or more, of the clinker. So, this effect can have a significant influence on the chemistry of the ALHEDAB Cement project.
Strength classes (grades) according EN 197-1 standard
We differ between different strength classes in order avoid mixing-up their resistance against stress in the later concrete. On the other hand we use this distinctive future to hallmark simultaneously the hardening interval time of those grades. That means we use a significant strength grad development up to two days with partial grad development or up to 28 days to reach their full strength grade. To avoid misusing are the bags imprinted by a colour code as shown above. It may sometimes be changed by cement manufacturers in several countries, but being according standard EN 197-1 those colours are obliging. So, to ALHEDAB Cement is strongly recommended using this colour code as well. Except of the chemical and mineralogical composition of cements is its finesses important for their technical features. Basically can be said, more fine cement develops a higher strength. The specific surface of cement particle, also called as BLAINE, will be used as the grade of fineness and is between 2,500 and 5,000 cm2/g. In the valid Europe standard for slow (L) and fast (R) hardened cements will be differed between the strength grades 32.5 / 42.5 / 52.5 MPa or N/mm² either. Gaining the best cement prices on the market means for ALHEDAB Cement to manufacture according the given grades, packed in the right bags and certifying the entire production without any irritations according the standard.
Cement Chemical Technology
At this point shall be mentioned at first, that this study does not refers to the wet cement process and wet technology. This older technology has been gone for decades and will not come back because of the very high fuel and energy consumption. So, in the antagonism to other feasibility study consultancies, IRD Swiss Research would never show any interests in wasting time and paperwork to discuss endless the advantages or disadvantages of the wet technology to manufacture cement nowadays. That means we only provide in the following cement technology considerations the dry process that is in the cement world of today a very well-known process, developed to its high-end status.
Cement manufacturing starts with quarrying the raw materials as we have discussed in the prior cement chemistry chapter. First of all, it will be needed the Limestone that occurs in the ALHEDAB reserved area of Nalut as a very rich in substance Limestone as a low mountainous belt of rock. Its chemistry shows a bright character of lime geodes inside, lays, fresh broken, bright and of light grey, very uniformly in this rock belt.
To look at one typically chemistry content line of this limestone we have chosen sample No. 4 drilled from the depth of 10-20m from a whole at the coordinates of N 31° 43’ 19.96” / E 10° 52’ 6.34” (APPENDIX X-1) shown as follows:
This sample was taken in 1975 during the big National geological survey, the National geographic and mining institute of Libya had ordered. The local sampling around Nalut area is quite rough, so right after project start, we have to raster a more compacted and closer drilling scheme in order to get better and more precisely analysis results from the planned quarry field of limestone around Mazuzah member formation.
The same we have to execute for the planned Gypsum quarry field N 32° 3’ 57.78” / E 10° 57’ 54.78” right of Umm al-Far direct in North of Nalut, only about 60 KM far from plant site. For that we gave order to analyse some found sample from ground bottom of the field. This would be a big advantage in the opposite to obtain the needed Gypsum from the largest Libyan Gypsum quarry, that is more than 250KM far from plant site.
Especially the CaO assay, more than 54% is one very good aspect to speak about a very suitable Limestone but there are also some small variations in assay of other chemical compounds, so it has to be clear that the transported Limestone into the plant stock has to be stored into a circular stock bin, where the raw material must be layered-up while moving-in on a circle to avoid chemical misplacements and differences in basic of the assays of the Limestone as much as possible (pre-blending storing). Longitudinal bins, as at older cement plants would be not good enough. That is why we decide installing one
circular stock tent with a diameter of 100m for each cement line separately.
Quarry Technology The ALHEDAB Limestone claim is a belt of stone rock with an open front end, edged in a wide of about 5 KM skewing to the road, shown here:
The clay, moved from 65KM disconnected Northern clay quarry at Wazen City, comes by truck into the plant in the same way as the Gypsum from the 60KM disconnected Gypsum quarry Umm Al-Far will be delivered, even on the same road.
As shown left, the overland transport belt brings the crushed Limestone from the quarry directly into a circular stock bin where the raw material will be layered-up in a circle bin, so called pre-blending storage. Pre-blending means the raw Limestone, collected from different places in the quarry, equipped with low chemical assay differences, will be mixed to a more homogeneous material, avoiding larger assay gaps in chemistry of Limestone. This fact is very important because otherwise the material matrix composition will be more difficult to handle in proportioning part to be controlled in the cement burning process where the Alite and Belite phases, mentioned as very important in the cement chemistry part of this study before, can be developed in the right time and amount. If we remember the time in the past where the most of manufacturers only had longitudinal bins for storing the crushed
Limestone, they faced strong problems in that. So, there is no way beside this technology as it is kind of the art of today’s storing the raw materials coming in from the quarry. This technology consist of a belt, coming from the top of the storage tent roof, bringing the material from quarry, down on a stacker what is circulating in a circle of 270 degree, a scraper below that, cutting horizontally the bin and stacks the raw material on an outgoing next belt that leads direct into the raw milling department, the next station within the plant site so far, considered next.
Additive Storage Technology
To provide the cement process with the needed amounts of additives has to be installed an additive storage facility. According the requirements of plant shall be delivered the Clay from the clay quarry onto the clay yard inside the plant by truck as distinguished from Limestone conveying way into the plant site the Clay and the Gypsum have to enter via a supplier gate directly onto clay and Gypsum yard. This is a special wish of the ALHEDAB management in order to avoid supplying the clay simultaneously with in- and outgoing cement trucks. It makes sense, especially because
the plant needs about 24% clay of about 3,120 TPD (tons per day). To carry this amount of clay needs about 80 trucks per day driving 65KM to and 65KM from the quarry into the plant. Multiplied with 330 operating days/year, the plant has to face more cost. That is why IRD Swiss recommends aspirating a third-party delivery contract for both, Clay and Gypsum. The same is valid for the less amount of Iron ore and the Sand, the cement process needs.
The picture shown below indicates a useful facility how to operate two independent workable additive yards and storages for a double line plant as ALHEDAB wants to establish. In the red yards will be kept the clay, in the white ones Gypsum is being
kept. Materials in all yards will be moved directly in a separate roller crusher by hydraulic sliding windlasses, no personnel staff needed. Crushed materials are being kept in roofed yards
Raw Material Proportioning
Before milling the raw materials and the process additives to be needed, all of those have to be proportioned in the right sufficient lots by weighing out their masses.
At this will be given by two separate belts according the LSF (Cement formula) the needed Limestone amount,
the Clay amount, the Sand amount and maybe some Iron Ore, on a weigh feeder,
where electronically will be balanced out all parts, controlled by the master control
Before milling the raw materials and the process additives to be needed, all of those have to be proportioned in the right sufficient lots by weighing out their masses.
At this will be given by two separate belts according the LSF (Cement formula) the needed Limestone amount,
the Clay amount, the Sand amount and maybe some Iron Ore, on a weigh feeder,
where electronically will be balanced out all parts, controlled by the master control